In general, if you want to work with date in PowerPivot you have to define a Dates table which contains, for each date, a number of column with data related to each day (for example, a sequential number identifying the number of working days elapsed since a particular reference date). If you have two column dates (like from and to) you have to import the same table twice, relate each Date table to one of these columns and then you can create the DAX formula in the main table by using the RELATED function get the number you need for each date (like the number of working days to calculate elapsed working days between two dates).
In other words, you have to shift your approach from a pure-formula based approach to a mixed model-driven plus DAX-formula approach. This was not so comfortable in Excel, but it is much easier (and powerful) using PowerPivot.
BTW: I wrote a whole chapter about dates calculation in the upcoming book "Microsoft PowerPivot for Excel 2010: Give Your Data Meaning"
Look at chapter 7 in Rough Cuts available here:
my.safaribooksonline.com/9780735650947
You should find some examples very similar to your needs.
Marco